Copper Sputtering Target – Withstand High Temperatures

Introduction

Copper (Cu) is one of the most widely used materials in thin film deposition processes due to its excellent electrical conductivity, thermal properties, and versatility. Copper sputtering targets, in particular, are essential in producing high-performance thin films for a variety of applications, including semiconductor devices, optical coatings, and electrical components. Although copper is highly regarded for its excellent conductivity, its ability to withstand high temperatures during the sputtering process is a critical factor in its selection as a target material. In this article, we will explore the properties of copper sputtering targets, their ability to endure high temperatures, and the benefits they provide in high-temperature sputtering applications.

For a broader view of materials capable of withstanding high temperatures, you can also check out the article Top 10 Sputtering Target Materials That Can Withstand High Temperatures.

Key Properties of Copper Sputtering Targets

Copper sputtering targets possess several key characteristics that make them suitable for thin film deposition, even in high-temperature environments:

  • High Electrical Conductivity: Copper is one of the best conductors of electricity, which is why it is commonly used in applications requiring efficient electrical performance, such as microelectronics and photovoltaics.
  • Thermal Conductivity: Copper has excellent thermal conductivity, which helps in efficiently distributing heat during the sputtering process, thus preventing local overheating that could degrade the target or affect the deposition quality.
  • Ductility and Malleability: Copper is a relatively soft and ductile metal, allowing it to be shaped and formed into sputtering targets with fine precision. Its malleability also allows the target to absorb some degree of thermal stress without cracking.
  • Moderate Melting Point: While copper’s melting point is lower than that of other metals like tungsten or molybdenum (about 1,984°F / 1,085°C), it still has a sufficiently high thermal tolerance for many sputtering applications that do not require extreme heat conditions.
  • Corrosion Resistance: Copper is naturally resistant to corrosion in many environments, though it can tarnish and oxidize when exposed to air. During sputtering, the oxidation of copper can sometimes affect film quality, which is why careful control of process parameters is necessary.

Why High-Temperature Resistance Matters for Copper Sputtering Targets

The sputtering process involves bombarding a target with high-energy ions, causing atoms from the target to be ejected and deposited onto a substrate. The temperature generated during this process can cause degradation in some materials, but copper sputtering targets are designed to endure these conditions. High-temperature resistance is crucial for several reasons:

  • Maintaining Target Stability: Copper sputtering targets need to withstand the thermal stress generated by the sputtering process without melting, deforming, or breaking apart. If a target fails under heat stress, it can lead to inconsistent deposition and poor film quality.
  • Ensuring Consistent Film Quality: As copper is bombarded by ions, it needs to remain stable and provide a consistent release of atoms for uniform film deposition. High-temperature resistance ensures that the copper target does not degrade, which could otherwise lead to uneven films with unwanted impurities.
  • Longevity of Sputtering Targets: Copper’s ability to perform well at elevated temperatures increases the operational lifespan of the sputtering target. This is important in industries with high-throughput production where reducing the frequency of target replacements is critical for minimizing downtime and costs.

Applications of Copper Sputtering Targets

Copper sputtering targets are widely used in industries that require the deposition of thin films with superior electrical and thermal conductivity. Key applications include:

  1. Semiconductor Manufacturing:
    Copper is used extensively in the production of integrated circuits (ICs) and microelectronic devices. Copper thin films are often deposited as interconnects due to their high conductivity, making them essential in semiconductor fabrication.
  2. Photovoltaic Cells:
    Copper sputtering targets are also employed in the manufacturing of thin-film solar cells, where their excellent conductivity helps in creating efficient solar energy conversion layers.
  3. Magnetic Coatings:
    Copper is used in magnetic thin film applications, particularly in data storage devices such as hard drives, where its conductivity and resistance to corrosion are critical for the performance of the device.
  4. Optical Coatings:
    Copper thin films are used in optical coatings for mirrors and other optical devices that require high reflectivity and durability.
  5. Electrical Components:
    Copper sputtering targets are used in the production of electrical components such as connectors, contacts, and conductors, where their high thermal and electrical conductivity is essential.

Conclusion

Copper sputtering targets are an excellent choice for many applications that require both high conductivity and resistance to moderate to high temperatures. While their melting point is not as high as some other materials like tungsten or molybdenum, copper’s thermal and electrical properties, along with its ductility, make it ideal for many thin-film deposition processes. As mentioned in the article Top 10 Sputtering Target Materials That Can Withstand High Temperatures, copper is among the key materials that offer reliable performance in a wide range of sputtering applications.

Choosing the right material for sputtering targets is crucial for ensuring the quality and longevity of thin films. Copper provides an optimal balance of conductivity, thermal stability, and cost-effectiveness, making it a top choice for industries that demand high-performance thin films.

Applications of High Purity Copper Sputtering Target

The copper sputtering target is a coating material made of metallic copper, which is suitable for DC bipolar sputtering, three-pole sputtering, four-stage sputtering, radio frequency sputtering, counter target sputtering, ion beam sputtering, and magnetron sputtering, etc. It can be applied to manufacture reflective films, conductive films, semiconductor films, capacitor films, decorative films, protective films, integrated circuits, displays, and etc. Compared with other precious metal sputtering targets, the price of copper targets is lower, so the copper target is the preferred target material under the premise of satisfying the function of the film layer.

Copper sputter targets are divided into the planar copper target and rotary copper target. The former is sheet-shaped, with round, square, and the like; the latter is tubular, and the utilization efficiency is high.

planar and rotory copper sputtering target

High-purity copper sputter targets are mainly used in electronics and information industries, such as integrated circuits, information storage, liquid crystal displays, laser memories, electronic control devices, etc.; they can be applied to the field of glass coating; they can also be applied to wear-resistant materials, high-temperature corrosion resistance, high-end decorative supplies and other industries.

Information storage industry: With the continuous development of information and computer technology, the demand for recording media in the world market is increasing, and the corresponding target media for recording media is also expanding. Related products include hard disks, magnetic heads, and optical disks. (CD-ROM, CD-R, DVD-R, etc.), a magneto-optical phase-change optical disc (MO, CD-RW, DVD-RAM).

Integrated circuit industry: In the field of semiconductor applications, sputtering targets are one of the main components of the world target market. They are mainly used for electrode interconnect film, barrier film, contact film, optical disk mask, capacitor electrode film, and resistive film, etc.

Flat-panel display industry: Flat panel displays include liquid crystal displays (LCDs), plasma displays (PDPs), and the like. At present, LCD is the main market in the flat panel display market, and its market share exceeds 85%. LCD is considered to be the most promising flat display device and is widely used in notebook monitors, desktop monitors and high definition televisions. The manufacturing process of the LCD is complicated, in which the reflective layer, the transparent electrode, the emitter and the cathode are all formed by a sputtering method, and therefore, the sputtering target plays an important role in the manufacture of LCD.

For more information, please visit https://www.sputtertargets.net/.

Image Gallery of SAM Sputter Targets

Stanford Advanced Materials (SAM) Corporation is a global supplier of various sputter targets such as metals, alloys, oxides, ceramic materials. We provide sputtering targets for a wide range of applications from ferromagnetic, complex oxides, and semiconducting films.

An Overview of Copper Sputtering Target

Copper sputtering targets, as part of vacuum coating materials, are widely applied in tool coating, optics coating, solar coating, and etc.  Copper targets can be put together with metallic copper because they are essentially the same–composed by Cu atoms.

Development of Copper

Copper is one of the earliest metals discovered by mankind and the first metal that humans began to use. Copper beads made of natural copper excavated by archaeologists in northern Iraq are supposed to have been more than 10,000 years old. Methods for refining copper from its ores were discovered around 5000BC and a 1000 or so years later it was being used in pottery in North Africa.

In modern industry, copper was widely used in the power and electronics industries. By the 1960s, copper used in these two industries accounted for 28%. By 1997, these two industries were still the main areas of copper consumption, accounting for Than 25%. Later, copper was widely used in electrical, light industry, machinery manufacturing, construction industry, transportation, and other fields. As far as America is concerned, copper is second only to aluminum in the consumption of non-ferrous materials. Copper has excellent performance and is easy to recycle and recycle. At present, there are already relatively complete recycled copper recycling systems in developed countries. For example, the output of recycled copper in the United States accounts for 60% of the total output, and Germany accounts for 80%.

Copper Sputtering Target Property

Copper is a chemical metal element with the symbol Cu. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement.

Material Type Copper
Symbol Cu
Color/Appearance Copper, Metallic
Melting Point 1,083 ℃
Density 8.96 g/cm3
Sputter DC
Type of Bond Indium, Elastomer
Comments Adhesion poor. Use interlayer (Cr). Evaporates using any source material.

From Metal Copper to Copper Sputter Target

The copper sputtering target is a kind of copper product made of the metal copper, and it is used in the sputter coating to produce copper thin film. Simply speaking, there are two methods to make copper sputtering target from metal copper.

Casting: melt the raw material of a certain distribution ratio, pour the alloy solution into a mold to form an ingot, and finally machine it to become a sputtering target. The method is smelted and cast in a vacuum.

Powder metallurgy: melt the raw material of a certain distribution ratio, cast it into an ingot and then pulverize it, isostatically press the powder, and then sintering it at a high temperature to finally form a target.

 

Powder metallurgy process
Powder metallurgy process

Basic Requirement of Copper SputterTarget

In general, when measuring whether the sputtering target meets the primary requirements, one would consider the following indicators:

Purity: Purity has a great influence on the performance of the film produced by sputter coating. Taking copper target as an example, the higher the purity is, the better the corrosion resistance and electrical and optical properties of the sputtered film are.

Impurity content: The impurities in the solid of the target material and the oxygen and water vapor in the stoma are the main pollution sources of the deposition film. Targets for different applications have different requirements of their impurity contents.

Density: The density of the target not only affects the sputtering rate but also affects the electrical and optical properties of the film. Thus, in order to reduce pores in the solids of the target and improve the properties of the sputtered film, the target is usually required to have a higher density.

Grain size and grain size distribution: For the same target, the sputtering rate of the fine-grained target is faster than that of the coarse-grained target; and the thickness of the target sputter-deposited film with a smaller difference in grain size (distributed uniformly) is more uniform.

Information provided by SAM Sputter Targets.