What Will Affect The Magnetron Sputtering Voltage?

Magnetic field

Magnetic field influences inversely the sputtering voltage. In other words, when the magnetic field on the surface of the sputtering target increases, the operating voltage of magnetron sputtering will decrease. It happens because the sputter-etched surface of the target gets closer to the strong magnetic field of the permanent magnet behind the target. To be noted, when the magnetic field strength increases above 0.1T, its effect on the sputtering voltage is no longer obvious.

In order to reduce the influence of this factor, the thickness of the sputtered material is not arbitrary, but limited. In general, thicker non-magnetic targets can be used in stronger magnetic fields.

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Material Type

Different target materials also affect the sputtering voltage. Here are examples of ITO, copper, aluminum, titanium, manganese, and chromium target.

Sputtering Target Sputtering Voltage
Indium Tin Oxide (ITO) ≈200V
Copper (Cu)
Aluminum (Al)
Titanium (Ti)
400~600V
Manganese (Mn)
Chromium (Cr)
>700V

Gas Pressure

Working gas pressure

Under the condition that various parameters (such as environmental conditions, power control panel parameters, etc.) remain unchanged, the increase of the working gas pressure will reduce the magnetic sputtering voltage.

Reactive gas pressure

On contrary, under the determined environment and constant power source, the increase of reactive gas pressure will result in the increase of magnetic sputtering voltage.

Distance Between Cathode & Anode

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The distance between the cathode and anode in vacuum gas discharge can have a certain effect on the sputtering voltage. If the distance is too large, the internal resistance of the equivalent gas discharge is mainly determined by the plasma equivalent internal resistance. Conversely, if the distance is too small, the internal resistance of the plasma discharge will be small.

When the magnetron target ignited and enters the normal sputtering, if the distance between the cathode and anode is too small, although the sputtering current has reached the process setting value, the target sputtering voltage is still low.

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Magnetrons & Magnets Used in Magnetron Sputtering

The planar magnetron is an exemplary “diode” mode sputtering cathode with the key expansion of a permanent magnet cluster behind the cathode. This magnet exhibit is organized so that the attractive field on the substance of the target is ordinary to the electric field in a shut way and structures a limit “burrow” which traps electrons close to the surface of the target. This enhances the effectiveness of gas ionization and compels the release plasma, permitting higher presence at the lower gas weight and attaining a higher sputter affidavit rate for Physical Vapor Deposition (PVD) coatings.

Although some distinctive magnetron cathode/target shapes have been utilized in magnetron sputtering processes, the most widely recognized target types are circular and rectangular. Circular magnetrons are all the more regularly found in littler scale “confocal” cluster frameworks or single wafer stations in group instruments. Rectangular Magnetrons are frequently found in bigger scale “in line” frameworks where substrates examine straightly past the focus on some type of carpet lift or transporter.

Color-online-Upper-Illustrations-of-circular-and-rectangular-planar-magnetron
Color-online-Upper-Illustrations-of-circular-and-rectangular-planar-magnetron. Greene, J.. (2017). Review Article: Tracing the recorded history of thin-film sputter deposition: From the 1800s to 2017. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films. 35. 05C204. 10.1116/1.4998940.

Most cathodes – including practically all circular and rectangular ones – have a straightforward concentric magnet design with the middle being one shaft and the edge the inverse. For the circular magnetron, this would be a generally little adjusted magnet in the middle, and an annular ring magnet of the inverse extremity around the outside with a hole in the middle. For the rectangular magnetron, the core one is typically a bar down the long hub (however short of the full length) with a rectangular “wall” of the inverse extremity and the distance around it with a hole in the middle. The crevice is the place the plasma will be, a roundabout ring in the circular magnetron or a lengthened “race track” in the rectangular.

The magnetron works with either an attractive arrangement – the middle could be north and the border might be south, or the other way around. Notwithstanding, in most sputter frameworks, there are various cathodes in reasonably close vicinity to one another, and you don’t need stray north/ south fields structured in the middle of the targets.

Those N/S fields ought to just be on the targets’ confronts, structuring the coveted attractive shafts there. Hence, it is completely attractive to verify all the cathodes in one framework are adjusted the same way, either all north on their borders or all south on their edges. What’s more, for offices with numerous sputter frameworks, it is similarly alluring to make all of them the same so cathodes can securely be traded between the frameworks without agonizing over magnet arrangement.

There are extra contemplations and choices in regard to the magnets. Most target materials are nonmagnetic and in this manner don’t meddle with the obliged attractive field quality. However, in the event that you are sputtering attractive materials, for example, iron or nickel, you will require either higher quality magnets, more slender targets, or both with a specific end goal to abstain from having the surface attractive field adequately shorted out by the attractive target material.

Past that, the magnet’s subtle elements, for example, attractive quality and crevice measurements, might be intended to enhance target material usage or to enhance consistency along the vital pivot of a rectangular target. It is even conceivable to utilize electromagnets rather than perpetual magnets, which can manage the cost of some level of programmable control of the attractive field, yet does, obviously, build many-sided quality and expense.

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How to Judge the Uniformity of PVD film?

PVD, Physical Vapor Deposition, is a general term for a series of coating methods. It includes two main categories: evaporation deposition coating and sputtering deposition coating. To specifictly classify it, there are vacuum ion evaporation, magnetron sputtering, MBE molecular beam epitaxy, sol gel method, etc.

For PVD vacuum coating with different principles, the concept of uniformity will have different meanings with the coating scale and film composition, and the factors affecting uniformity are also different. In general, film uniformity can be understood from the following three aspects.

Uniformity in thickness (roughness)

From the scale of optical films (that is, 1/10 wavelength as a unit, about 100A), vacuum coating can easily control the roughness within 1/10 of the wavelength of visible light, and the uniformity is quite good.

But if it refers to the uniformity on the atomic layer scale (that is to say, to achieve 10A or even 1A surface flatness), the roughness of the film can be good or bad, which is also the main technical content and technical bottleneck in the current vacuum coating.

The thickness uniformity is mainly determined by the following points: 1) the degree of lattice matching between the substrate material and the target material; 2) the surface temperature of the substrate; 3) evaporation power, speed; 4) vacuum degree; 5) coating time, thickness.

Thin film thickness

Uniformity in chemical composition

In thin films, the atomic composition of compounds can easily produce non-uniform properties due to their small size. For example, in the process of preparing SiTiO3 thin films, if the material ratio and environment are not strictly controlled, the components of the prepared surface may not be SiTiO3, but Sr, Ti, and O may exist in other proportions.

The uniformity of the components of the evaporation coating is not easy to guarantee, and the specific factors that can be adjusted are the same as the above, but due to the limitation of the principle, for the non-single component coating, the uniformity of the components of the evaporation coating is not good.

Uniformity of lattice order

This determines whether the film is single crystal, polycrystalline, or amorphous. It is also a hot issue in vacuum coating technology.

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